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31.
The kinetic fractionation of open-water evaporation against the stable water isotope H_2 ~(18)O is an important mechanism underlying many hydrologic studies that use ~(18)O as an isotopic tracer. A recent in-situ measurement of the isotopic water vapor flux over a lake indicates that the kinetic effect is much weaker(kinetic factor 6.2‰) than assumed previously(kinetic factor14.2‰) by lake isotopic budget studies. This study investigates the implications of the weak kinetic effect for studies of deuterium excess-humidity relationships, regional moisture recycling, and global evapotranspiration partitioning. The results indicate that the low kinetic factor is consistent with the deuterium excess-humidity relationships observed over open oceans.The moisture recycling rate in the Great Lakes region derived from the isotopic tracer method with the low kinetic factor is a much better agreement with those from atmospheric modeling studies than if the default kinetic factor of 14.2‰ is used. The ratio of transpiration to evapotranspiration at global scale decreases from 84±9%(with the default kinetic factor) to 76±19%(with the low kinetic factor), the latter of which is in slightly better agreement with other non-isotopic partitioning results.  相似文献   
32.
Isotopes of water (2H/1H and 18O/16O) are commonly used to trace hydrological processes such as moisture recycling, evaporation loss, and moisture source region and often vary temporally in a given region. This study provides a first‐ever characterization of temporally variable precipitation mechanisms of San Cristóbal Island, Galápagos. We collected fog, rain, and throughfall samples over three field seasons to understand the mechanisms driving seasonal‐ and event‐based variability in the isotopic composition of precipitation in Galápagos. We establish that fog is a common phenomenon in San Cristóbal, especially during the dry season, and we found that fog, compared with cocollected rainfall, is consistently enriched. We further suggest that the relative contribution of fog formed via different mechanisms (orographic, advective, radiation) varied seasonally. We found that the source region is the most dominant control of the isotopic composition of rainfall in the Galápagos at both the seasonal and event scales, but subcloud evaporative processes (the nontraditional manifestation of the amount effect) became a dominant control on the isotopic composition of rainfall during the dry season. Overall, our findings suggest that understanding seasonally variable water‐generating mechanisms is required for effective water resource management in San Cristóbal Island and other semiarid island ecosystems under current and future regimes of climate change.  相似文献   
33.
王熠熙  李赫  王博  杨朋涛  王俊  向阳  王喜龙  李悦 《地震》2018,38(1):128-138
基于临界慢化理论, 以2013年7月22日甘肃岷县—漳县MS6.6地震前南北构造带及邻区水氡浓度观测资料为例, 逐一计算了表征临界慢化现象的自相关系数和方差。 研究结果表明, 2013年岷县—漳县MS6.6地震前, 10个台点水氡浓度资料表现出较明显的临界慢化现象, 且出现慢化现象的观测点空间分布具有一定丛集性, 慢化持续时间呈现出由南向北迁移的特征。 综合分析认为, 临界慢化方法可以有效识别水氡资料蕴含的慢化信息, 这些早期异常信号对判定前兆异常所处阶段以及深入理解前兆资料变化的物理内涵具有重要的科学意义。  相似文献   
34.
We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AICC] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   
35.
中国火山温泉主要分布在吉林长白山、云南腾冲和黑龙江五大连池等火山区。这些火山虽然处于休眠状态,但大面积的温泉分布指示着岩浆房存在的可能性。本文总结了前人研究成果,分析了中国主要火山区温泉气体地球化学特征,并探讨了温泉气体在火山监测中的应用。长白山、腾冲和五大连池火山区温泉气体地球化学性质类似,都以CO2为主要气体,含量在80%以上,最高可达99%以上,其它气体组分包括CH4、N2、O2、SO2、H2S、He和H2等。长白山火山温泉气体中氦同位素比值(3He/4He)最高,约为4—6RA,CO2中碳同位素比值(δ13C)为-7.9‰—-1.3‰,CH4中碳同位素为-48.0‰—-28.7‰;腾冲火山温泉气体氦同位素比值为3—5.5RA,CO2中的碳同位素为-6.49‰—-2.07‰,CH4中碳同位素为-23.5‰—-9.3‰;五大连池火山温泉气体氦同位素比值约为3RA,CO2中的碳同位素比值为-9.6‰—-3.1‰,CH4中碳同位素为-47.2‰—-44.4‰。3个火山区的温泉气体均显示地幔来源的岩浆气体特征,并在上升运移过程中受地壳或古俯冲物质的影响。  相似文献   
36.
This paper presents the history and cryostratigraphy of the upper permafrost in the High‐Arctic Adventdalen Valley, central Svalbard. Nineteen frozen sediment cores, up to 10.7 m long, obtained at five periglacial landforms, were analysed for cryostructures, ice, carbon and solute contents, and grain‐size distribution, and were 14C‐ and OSL‐dated. Spatial variability in ice and carbon contents is closely related to the sedimentary history and mode of permafrost aggradation. In the valley bottom, saline epigenetic permafrost with pore ice down to depths of 10.7 m depth formed in deltaic sediments since the mid‐Holocene; cryopegs were encountered below 6 m. In the top 1 to 5 m, syngenetic and quasi‐syngenetic permafrost with microlenticular, lenticular, suspended and organic‐matrix cryostructures developed due to loess and alluvial sedimentation since the colder late Holocene, which resulted in the burial of organic material. At the transition between deltaic sediments and loess, massive ice bodies occurred. A pingo developed where the deltaic sediments reached the surface. On hillslopes, suspended cryostructure on solifluction sheets indicates quasi‐syngenetic permafrost aggradation; lobes, in contrast, were ice‐poor. Suspended cryostructure in eluvial deposits reflects epigenetic or quasi‐syngenetic permafrost formation on a weathered bedrock plateau. Landform‐scale spatial variations in ground ice and carbon relate to variations in slope, sedimentation rate, moisture conditions and stratigraphy. Although the study reveals close links between Holocene landscape evolution and permafrost history, our results emphasize a large uncertainty in using terrain surface indicators to infer ground‐ice contents and upscale from core to landform scale in mountainous permafrost landscapes.  相似文献   
37.
广西土壤有机质空间变异特征及其影响因素研究   总被引:2,自引:0,他引:2  
基于广西第二次土壤普查的270个土壤剖面资料,结合1∶50万数字化土壤类型图、土地利用类型图和气象监测数据等资料,利用地统计学和逐步回归分析等方法对广西表层土壤有机质空间变异特征及其影响因素进行了探究。结果表明:广西表层土壤有机质平均含量为3.11±2.19%,变异系数为70.72%,空间分布呈北高南低的趋势。广西表层土壤有机质空间分布受到自然和人为因素的共同影响,土壤类型、成土母质、海拔、土地利用、气候和坡度6个环境因子对全区土壤有机质含量变异的综合解释能力为47.9%。其中,土壤类型是最重要的影响因素,能独立解释其变异的36.0%,海拔和成土母质分别能独立解释28.5%和15.8%。气温对广西土壤有机质空间分布的影响比降水量更加显著,从而造成了广西土壤有机质整体呈南低北高的趋势。同时,土壤有机质对气温的敏感性在一定程度上受到降雨量的制约。此外,研究区农业耕作管理等因素对土壤有机质的影响也不容忽视。  相似文献   
38.
基于甘肃河西走廊15个国家基准基本站点提供的1966年1月1日~2018年12月31日春季(3~5月)逐日最低气温值数据,利用线性回归分析方法、Spline空间插值法和Mann-Kendall趋势和突变检验法,探讨了河西走廊地区1966—2018年春季(3~5月)寒潮频次变化及其影响因子。研究表明:(1) 1966—2018年河西走廊地区春季(3~5月)单站寒潮频次总体呈现下降趋势〔–0.098次·(10 a)–1〕,其中1980—2010年寒潮频次呈显著下降趋势,2010年之后下降趋势变缓,未通过显著性检验;区域寒潮53 a来频次总体呈缓慢下降趋势〔–0.015次·(10 a)–1〕。(2) 近53 a河西走廊地区春季三个月中,单站寒潮总量4月>3月>5月,其中4月、5月寒潮频次下降不明显,3月频次下降显著。(3) 空间上,大致以北大河和黑河干流为界,两河中间区域春季寒潮频次低,而北大河以北和黑河干流以东区域则是寒潮高值区,走廊外围地区寒潮频次较高,且大多呈显著下降趋势,寒潮频次与气温距平存在明显负相关关系,内部地区变化趋势不明显。(4) 河西地区春季寒潮频次受气候变暖、地形和大气环流的影响,寒潮频次变化趋势存在地区差异。研究可提高对甘肃河西走廊寒潮演化过程的认知,为河西走廊气候变化的进一步研究奠定基础。  相似文献   
39.
作为重要的土壤物理性质,膨胀性在影响土壤导水性、持水性、抗蚀性以及土壤结构的形成和发育等方面发挥着重要作用。为了探讨生物土壤结皮(BSCs)土壤的膨胀特性及其主要影响因素,针对黄土高原风沙土和黄绵土两种典型土壤,利用膨胀仪测定并比较了有、无藓结皮及其在不同因素(初始含水量、干湿循环、冻融循环、温度)下膨胀率的差异,分析了BSCs对土壤膨胀性的影响及其与环境因素和BSCs性质的关系。结果显示:风沙土上藓结皮的膨胀率为1.93%,较无结皮增加了8.65倍;而黄绵土上藓结皮的膨胀率为2.05%,与无结皮相比降低了76.68%。藓结皮的生物量和厚度与其膨胀率在风沙土上均呈线性正相关关系(P < 0.05),在黄绵土上分别呈二次函数(P=0.02)和线性正相关关系(P=0.02)。初始含水量同时影响了土壤最大膨胀率和稳定膨胀时间,影响程度风沙土远大于黄绵土(包括藓结皮和无结皮);干湿循环次数对无结皮土壤膨胀率的影响程度大于藓结皮土壤,其中风沙土和黄绵土上无结皮的膨胀率分别是50.00%~620.00%和-2.28%~10.81%,而两种土壤上藓结皮的膨胀率分别是-5.70%~10.88%和-10.24%~-21.46%;冻融循环下4种土壤的膨胀率均有不同程度的降低,降幅为0~18.54%。黄绵土无结皮的膨胀率受温度影响程度较大,50℃下黄绵土无结皮的膨胀率分别是25℃和35℃下的1.17倍和1.21倍。BSCs显著地改变了风沙土和黄绵土表层的膨胀性,其影响的程度和方向取决于土壤类型。同时,BSCs的膨胀性受含水量、温度、干湿以及冻融循环等关键因素影响。  相似文献   
40.
边艳  周春山  胡锦灿 《热带地理》2020,40(5):832-842
以2014年广州市中产阶层聚居区24个街道、50个社区进行的问卷调查和深度访谈资料为数据源,从住房需求意愿与区位选择方面分析了广州中产阶层住房选择,并运用多元Logistic回归分析法对其影响因素进行研究。研究发现:1)广州市中产阶层住房区位选择表现出明显的“向中心城区”性;2)现居住现状(人均住房面积、现小区区位、现小区建成年代、现居住时间)、家庭生命周期(年龄、家庭规模、子女数量)和经济水平(家庭年总收入、个人年总收入、私家车拥有量)等因素对中产阶层住房需求意愿具有显著影响;3)家庭生命周期(年龄、家庭规模)、个体因素(教育程度、户籍地)等要素对中产阶层住房区位选择具有显著影响。4)制度因素、区位因素和个体因素共同影响着广州市中产阶层住房区位选择。  相似文献   
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